Batch-Injection Amperometric Determination of Pyrogallol in Biodiesel Using a Multi-Walled Carbon Nanotube Modified Electrode

AUTOR(ES)

Cardoso, Rafael M., Dornellas, Rafael M., Lima, Ana P., Montes, Rodrigo H. O., Richter, Eduardo M., Munoz, Rodrigo A. A.

FONTE

J. Braz. Chem. Soc.

DATA DE PUBLICAÇÃO

2017-09

RESUMO

This work demonstrates the application of batch-injection analysis (BIA) with amperometric detection on a multi-walled carbon nanotube (MWCNT) modified electrode for the sensitive determination of the antioxidant pyrogallol in biodiesel. Samples were diluted in electrolyte (0.1 mol L-1 HClO4) before injection using an electronic micropipette on the BIA cell. The size effect of MWCNTs on electrochemical oxidation of pyrogallol was investigated and 3.5-fold increase in the amperometric sensitivity using the modified electrode with MWCNTs of shorter dimensions was obtained. This result was in agreement with cyclic voltammetry and electrochemical impedance spectroscopy measurements. After optimization of BIA parameters for the amperometric detection on the MWCNT-modified electrode, the proposed method presented a linear range from 0.3 to 1000 µmol L-1, detection limit of 0.013 µmol L-1, precision of 3%, and sample throughput of 240 h-1. Spiked biodiesel samples were analyzed and recovery values between 95-99% were obtained.

Documentos Relacionados

• A sensitive determination of acetaminophen in pharmaceutical preparations and biological samples using multi-walled carbon nanotube modified glassy carbon electrode
• Developing a sensor for the simultaneous determination of dopamine, acetaminophen and tryptophan in pharmaceutical samples using a multi-walled carbon nanotube and oxadiazole modified glassy carbon electrode
• A multi-walled carbon nanotube-modified glassy carbon electrode as a new sensor for the sensitive simultaneous determination of paracetamol and tramadol in pharmaceutical preparations and biological fluids
• Functionalization of Multi-Walled Carbon Nanotube and Mechanical Property of Epoxy-Based Nanocomposite
• Surface properties of oxidized and aminated multi-walled carbon nanotubes