As cumarinas do pterocaulon balansae, Chodat

AUTOR(ES)
DATA DE PUBLICAÇÃO

1981

RESUMO

Starting from an hexane/ethyl ether extract of the aereal parts of Pterocaulon balansae, Chodat, we isolated the five following coumarins: 5-(3 -methyl-2 ,3 -butenyloxy)-6,7-methylenedioxycoumarin; 5-(2 ,3 -epoxy-3 -methylbutyloxy)-6,7-methylenedioxycoumarin; 5-(2 ,3 -dihydroxy-3 -methylbutyloxy)-6,7-methylenedioxycoumarin; 6-methoxy-7-(2 ,3 -epoxy-3 -methylbutyloxy)coumarin; and 6-methoxy-7-(3 -methyl-2 ,3 -dihydroxybutyloxy)coumarin. Three of these coumarins are new. The structures of these coumarins were determined by the usual spectroscopic methods, and by chemical methods. A study of two of the coumarins using carbon-13 magnetic resonance emphasizes the substituent effects upon the carbon chemical shifts, allowing the precise allocation of these substituents on the coumarin ring.

ASSUNTO(S)

analise cromatografica quimica organica plantas

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