Análise por componentes principais de espectros nexafs na especiação do molibdênio em catalisadores de hidrotratamento

AUTOR(ES)
FONTE

Química Nova

DATA DE PUBLICAÇÃO

2010

RESUMO

Bulk and supported molybdenum based catalysts, modified by nickel, phosphorous or tungsten were studied by NEXAFS spectroscopy at the Mo L III and L II edges. The techniques of principal component analysis (PCA) together with a linear combination analysis (LCA) allowed the detection and quantification of molybdenum atoms in two different coordination states in the oxide form of the catalysts, namely tetrahedral and octahedral coordination.

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