A NEW HOMOGENEOUS ELECTROCATALYST FOR ELECTROCHEMICAL CARBONYLATION OF METHANOL TO DIMETHYL CARBONATE
AUTOR(ES)
Wang, Xiaoyan, Jia, Gan, Yu, Yuting, Gao, Yanfang, Zhang, Wen, Wang, Hong, Cao, Zhenzhu, Liu, Jinrong
FONTE
Quím. Nova
DATA DE PUBLICAÇÃO
2015-03
RESUMO
Electrosynthesis of dimethyl carbonate (DMC) from methanol and carbon monoxide using an Cu(phen)Cl2 catalyst was achieved at room temperature and atmospheric pressure. The catalytic activity of the ligand 1,10-phenanthroline (phen) and the catalytic system were analyzed. The IR characterization results for the complex catalyst showed that copper ions were coordinated by nitrogen atoms of phen. In addition, the effects of the influencing factors, such as reaction time (t), reaction temperature (T) and the surface area of the working electrode (SWE) were studied.
Documentos Relacionados
- Synthesis of dimethyl carbonate in supercritical carbon dioxide
- Electrochemical degradation of dimethyl phthalate ester on a DSA® electrode
- Synthesis of glycerol carbonate by transesterification of glycerol and dimethyl carbonate over KF/γ-Al2O3 catalyst
- A new mechanism for the aerobic catabolism of dimethyl sulfide.
- New Pseudomonad Utilizing Methanol for Growth