Aromatic Amines
Mostrando 1-12 de 74 artigos, teses e dissertações.
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1. OBTENÇÃO DE AMINAS PRIMÁRIAS A PARTIR DA REDUÇÃO DE NITROCOMPOSTOS AROMÁTICOS VIA PROTOCOLOS DE REAÇÕES SUSTENTÁVEIS EM MEIO AQUOSO
Aromatic amines are important intermediates in the industry to produce a wide array of products, and the reduction of aromatic nitro compounds is the main methodology for their preparation. Considering this fact, the objective of this review is to describe the development of sustainable methodologies for the reduction of aromatic nitro compounds for their re
Química Nova. Publicado em: 2022
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2. Mechanistic Investigation of DBU-Based Ionic Liquids for Aza-Michael Reaction: Mass Spectrometry and DFT Studies of Catalyst Role
1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-based ionic liquids (ILs) has exhibited a high catalytic activity in the aza-Michael reactions compared to conventional catalysts and with imidazole-based ILs. In the present work DBU-based ILs showed high catalytic potential for aza-Michael addition of aromatic amines to 2-cyclohexen-1-one under solvent-free conditio
J. Braz. Chem. Soc.. Publicado em: 2020-09
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3. Magnetic Solid-Phase Extraction Combined with Dispersive Liquid-Liquid Microextraction Followed by HPLC for Determination of Four Aromatic Amines Released from Azo Dyes in Paper Samples
A novel extraction technique combining dispersive liquid-liquid microextraction (DLLME) with magnetic solid-phase extraction (MSPE) is presented for pre-concentration of four primary aromatic amines (PAAs) released from azo dyes in paper samples prior to high performance liquid chromatography (HPLC). n-Octanol was used as the extractant and hydrophobic oleic
J. Braz. Chem. Soc.. Publicado em: 2018-04
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4. Spectroscopic Characterization of Charge Transfer Complexes of TCNE with Aromatic Amines - The First Step of Tricyanovinylation Reaction
The first step of electrophilic aromatic substitution reactions generally involves the formation of charge transfer complexes. Tetracyanoethylene (TCNE) in the presence of aromatic amines forms π-type complexes that subsequently lead to tricyanovinylation reaction. Although this kind of reaction was investigated in the past, the spectroscopic characterizati
J. Braz. Chem. Soc.. Publicado em: 2017-09
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5. Eco-Friendly, Catalyst and Solvent-Free, Synthesis of Acetanilides and N-Benzothiazole-2-yl-acetamides
An expeditious and green synthesis of acetamides in a solvent-free simple way is described, without catalyst or additives, and in good yield by an instantaneous reaction of anilines or 2-aminothiazoles and acetic anhydride without external heating, and with simple purification. Sixteen substituted acetanilides and four N-benzothiazole-2-yl-acetamides were fo
J. Braz. Chem. Soc.. Publicado em: 2017-06
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6. AVALIAÇÃO DO RADICAL N,N-DIETIL-1,4-FENILENODIAMINO (DEPD•+) COMO SONDA ESPECTROFOTOMÉTRICA PARA DETERMINAÇÃO DA CAPACIDADE ANTIOXIDANTE EM BEBIDAS
AbstractMany well-established methods for determining the antioxidant capacities in several samples have been described in literature. However, DPPH (2,2-diphenyl-1-picrylhydrazyl) and ABTS (2,2'-azino-bis(3-ethylbenzothiazoline-6-sulphonic acid)) are the main two methods that utilize radicals as spectrophotometric probes for analysis. Nevertheless, these me
Quím. Nova. Publicado em: 2015-08
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7. Microbial dynamics during azo dye degradation in a UASB reactor supplied with yeast extract
The present work aimed to investigate the microbial dynamics during the anaerobic treatment of the azo dye blue HRFL in bench scale upflow anaerobic sludge bed (UASB) reactor operated at ambient temperature. Sludge samples were collected under distinct operational phases, when the reactor were stable (low variation of color removal), to assess the effect of
Braz. J. Microbiol.. Publicado em: 2014-12
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8. Cloning, characterization and expression of a novel laccase gene Pclac2 from Phytophthora capsici
Laccases are blue copper oxidases (E.C. 1.10.3.2) that catalyze the one-electron oxidation of phenolics, aromatic amines, and other electron-rich substrates with the concomitant reduction of O2 to H2O. A novel laccase gene pclac2 and its corresponding full-length cDNA were cloned and characterized from Phytophthora capsici for the first time. The 1683 bp ful
Braz. J. Microbiol.. Publicado em: 08/04/2014
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9. Desenvolvimento de métodos para determinação de aminas aromáticas em amostras têxteis por eletroforese capilar / Development of methodology for determination of aromatic amines in textiles matrices by capillary electrophoresis
Os corantes que apresentam grupos cromóforos do tipo azo (N=N) são amplamente empregados em numerosas aplicações na indústria, para colorir vários bens de consumo, dentre eles os têxteis. Entretanto, pelo fato de formarem aminas aromáticas carcinogênicas, quando a ligação N=N é rompida, seu uso está sujeito à legislação. Levando em considera�
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 19/03/2012
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10. SYNTHESIS,CHARACTERIZATION AND THEORETICAL STUDY OF ORTHO-SUBSTITUTED SCHIFF BASES AND THEIR COPPER(II) COMPLEXES AS POTENTIAL ANTITUMOR AGENTS / SÍNTESE, CARACTERIZAÇÃO E ESTUDO TEÓRICO DE BASES DE SCHIFF ORTO-SUBSTITUÍDAS E SEUS COMPLEXOS DE COBRE(II) COMO POTENCIAIS AGENTES ANTITUMORAIS
Nowadays, the neoplastic processes have been one of the most concern diseases. The malignance tumor, also called cancer, is the most aggravating pathological process, responsible for the death of the patient in most cases. In this context, several drugs have been designed with the objective to eliminate the cancer cells selectively; among them, some coordina
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 24/02/2012
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11. Influência do período de maturação e das estações do ano nos parâmetros físico-químicos e microbiológicos do queijo Minas artesanal da região do Serro
Minas traditional Serro cheese is a product that has a high consumption and appreciation in Brazil. The main objective of this work was to verify the ripening and dry and rainy seasons influence on hygienical-sanitary indicators, pathogenic microorganisms, Staphylococcal enterotoxins and physicochemical characteristics of this cheese to find out the microbio
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 27/05/2011
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12. Princípios da determinação de íons em amostras por eletroforese capilar.
ABSTRACT: This work presents theory and applications in capillary electrophoresis. This technique is a powerful tool representing a large saving in chemicals (0.5 to 4 nL s-1 flux), samples (1 to 100 nL), and method development time. In addition, this work pictures applications such as separation and determination of analytical compounds. Recent reviews were
Planaltina. Publicado em: 2011