Alcoholysis
Mostrando 1-12 de 25 artigos, teses e dissertações.
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1. Microscale direct transesterification of microbial biomass with ethanol for screening of microorganisms by its fatty acid content
Abstract We present an improved method of direct transesterification suitable for the quantitative analysis of multiple dry samples for its fatty acid content, using a minimal amount of biomass and reactants. The method features an acid-catalyzed direct alcoholysis of microgram samples of dry biomass; the rationale behind the solvent and reagent proportions
Braz. arch. biol. technol.. Publicado em: 15/04/2019
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2. Synthesis, characterization and antibacterial activity of novel poly(silyl ether)s based on palm and soy oils
Abstract In this research, palm oil and soy oil were used as a natural polyol to prepare novel poly(silyl ether)s. Palm oil and soy oil were first converted to monoglyceride by one step via alcoholysis process in the presence of 0.1% CaO as a catalyst. The monoglycerides were characterized by Fourier transform infrared spectrometer (FT-IR), nuclear magnetic
Polímeros. Publicado em: 29/11/2018
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3. Phytotoxicity of Perlatolic Acid and Derivatives
ABSTRACT Perlatolic acid (1), methyl perlatolate (2), and the products of perlatolic acid alcoholysis-namely, methyl, ethyl, n-propyl, iso-propyl, n-butyl, sec-butyl, tert-butyl, n-pentyl, and n-hexyl 2-hydroxy-4-methoxy-6-n-pentylbenzoate (3-11)-were evaluated for their herbicidal potential on Lactuca sativa L. (lettuce) and Allium cepa L. (onion) seeds. Th
Braz. arch. biol. technol.. Publicado em: 01/08/2016
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4. Molecular Sieves Mediated Green Per-O-Acetylation of Carbohydrate Templates and Lipase Catalyzed Regioselective Alcoholysis of 2,3,5-Tri-O-Acetyl-D-Ribonolactone
The per-O-acetylation of D-ribono-1,4-lactone and representative carbohydrates through the combination of acetic anhydride and molecular sieves under solvent-free conditions is demonstrated. The use of 13X/KCl molecular sieves as the heterogeneous catalyst was found to be more efficient than the excess of pyridine normally employed in the conventional method
J. Braz. Chem. Soc.. Publicado em: 2015-04
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5. Produção de lipases de Aspergillus niger e Aspergillus fumigatus através de fermentação em estado sólido, avaliação da especificidade do substrato e seu uso em reações de esterificação e alcoólise: evaluation of substrate specificity and use in esterification and alcoholysis reactions
Filamentous fungi were cultured under solid state fermentation of soybean residues to produce lipases. Enzymes produced by Aspergillus niger esterified oleic and butyric acids in the presence of ethanol, while enzymes produced by Aspergillus fumigatus demonstrated no esterification activity toward lauric acid. In case of A. niger, direct lyophilization of fe
Quím. Nova. Publicado em: 2014-06
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6. Resinas alquídicas base água emulsionadas por inversão de fase
This work reports the use of emulsion phase inversion technique to prepare waterbased alkyd resins, eliminating the use of organic solvents for dilution of this type of polymer, largely used in paint manufacture. First, alkyd polymers were synthesized by alcoholysis of vegetable oils and polyols in the presence of catalysts and subsequent esterification, con
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 2011
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7. Estudo do processo enzimático de produção de biodiesel a partir de óleos e gorduras residuais de fritura. / Study on enzymatic process of biodiesel production from waste frying oils and fats.
A utilização de biodiesel como combustível tem apresentado um potencial promissor no mundo inteiro. Apesar dos possíveis benefícios ambientais no emprego de óleos vegetais para conversão em biodiesel como substituto ao diesel, barreiras do ponto de vista econômico e ético, como concorrência do uso do solo e água com culturas alimentares e para out
Publicado em: 2010
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8. Experimental determination of the data kinetics of transesterification reaction of vegetable oils / Determinação experimental dos dados cineticos da reação de transesterificação de oleos vegetais
The general objective of this study was to contribute with the biodiesel production. More specifically, the purpose is to obtain experimental parameters kinetics of transesterification reaction for alcoholysis reaction of various vegetable oils produced in Brazil, such as palm oil, waste frying, coconut oil, soybean oil and castor oil, being employed various
Publicado em: 2009
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9. Biocombustíveis a partir de óleos e gorduras: desafios tecnológicos para viabilizá-los
Periodically, during petroleum shortage, fatty acids and their derivatives have been used as alternative fuels to those derived from petroleum. Different approaches have been proposed, including the use of neat fats and oils or their derivatives. Indeed, the utilization of biodiesel produced by alcoholysis of triacilglycerides or esterification of fatty acid
Quím. Nova. Publicado em: 2009
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10. Produção de biodiesel a partir da alcoólise do óleo de palma / The production of biodiesel from the alcoholysis of palm oil
No presente trabalho foi investigada a produção de biodiesel a partir da alcoólise do óleo de palma catalisada por lipase imobilizada comercial. O efeito da razão molar de álcool:óleo, da forma de adição do álcool (única e escalonada), da temperatura de reação, da concentração de enzima, do tipo de álcool (metanol e etanol), do tipo de enzima
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 28/11/2008
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11. Obtenção de biodiesel por transesterificação enzimática de óleo de soja com etanol empregando t-butanol como solvente / Biodisel production by enzymatic transesterification of soybean oil with ethanol using t-butanol as a solvent
Neste estudo foi investigada a alcoólise enzimática do óleo de soja com etanol, utilizando t-butanol como solvente e enzimas imobilizadas Lipozyme TL IM, Lipozyme RM IM e Novozym 435 como catalisadores. As reações foram realizadas em um reator batelada fechado acoplado a um condensador e com constante agitação. Foram avaliadas a influência do t-butan
Publicado em: 2008
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12. Studies of residual oils originating from of processo f fry and qualification of those for obtaining of monoésteres (Biodiesel). / Estudos de óleos residuais oriundos de processo de fritura e qualificação desses para obtenção de monoésteres (Biodiesel).
Biodiesel is now considered as an important option for full or partial diesel fossil replacement. At the same time, biodiesel is a renewable and an environmentally friendly fuel. This work has as goal to employ residual vegetable oils for biodiesel production and evaluate its viability as raw material. For that, some initial steps were considered in order to
Publicado em: 2008