Vapor Liquid Equilibrium
Mostrando 1-12 de 82 artigos, teses e dissertações.
-
1. MEASUREMENTS AND THERMODYNAMIC MODELING OF VAPOR-LIQUID EQUILIBRIA FOR BINARY SYSTEMS OF ISOPROPYL CHLOROACETATE WITH CYCLOHEXANE, ISOPROPANOL AND BENZENE AT 101.3 kPa
Abstract In this work, the vapor-liquid equilibrium experimental data for the systems of isopropyl chloroacetate + isopropanol, isopropyl chloroacetate + cyclohexane and isopropyl chloroacetate + benzene were measured by a modified Rose-type recirculating still under the pressure of 101.3 kPa. The thermodynamic consistency of the measured data was verified
Braz. J. Chem. Eng.. Publicado em: 13/01/2020
-
2. QUADRATURE ALGORITHMS FOR PHASE EQUILIBRIUM OF CONTINUOUS MIXTURES
Abstract Several methods for computing the Gauss-Christoffel quadrature used for the adaptive characterization of continuous mixtures were compared as to their efficiency and robustness. Two mixtures with molar fraction distribution given by truncated gamma distributions were used. We analyzed the Product-Difference, the Golub-Welsch, the Long Quotient-Modif
Braz. J. Chem. Eng.. Publicado em: 09/12/2019
-
3. PHASE BEHAVIOR DATA AND THERMODYNAMIC MODELING OF THE BINARY SYSTEM {CO2 + COUMARIN} AT HIGH PRESSURES
Abstract In this work, vapor - liquid (VLE) equilibrium for the binary system carbon dioxide (1) + coumarin (2) at high pressures was measured by a static synthetic method using a variable-volume view cell. Experimental data were obtained in the temperature range of 318 - 338 K and pressures up to 20 MPa. Coumarin molar fraction ranged from 3.0x10-3 to 6.0x1
Braz. J. Chem. Eng.. Publicado em: 30/09/2019
-
4. Analysis and extension of the Furter equation, and its application in the simulation of saline extractive distillation columns
ABSTRACT Simulation of saline extractive distillation columns is a difficult task owing to the high nonlinearity of the rigorous models that represent these systems. The use of simple models to obtain initial estimates of equilibrium compositions may improve the stability and rate of convergence. One of the simplest models to study the vapor-liquid equilibri
Braz. J. Chem. Eng.. Publicado em: 2017-04
-
5. MODELING AND SIMULATION OF A BENZENE RECOVERY PROCESS BY EXTRACTIVE DISTILLATION
Abstract Extractive distillation processes with N-formylmorpholine (NFM) are used industrially to separate benzene from six carbon non-aromatics. In the process studied in this work, the stream of interest consists of nearly 20 different hydrocarbons. A new set of NRTL parameters was correlated based on literature experimental data. Both vapor-liquid equilib
Braz. J. Chem. Eng.. Publicado em: 2015-03
-
6. Measurement and correlation of isobaric vapor-liquid equilibrium for the binary system of cyclopentane and tetrahydrofuran
Isobaric vapor-liquid equilibrium (VLE) data for the cyclopentane and tetrahydrofuran (THF) system were measured at 101.3 kPa by using an equilibrium still. Thermodynamic consistency of the experimental data was confirmed by means of the Herington method. The experimental data were correlated and calculated by the Margules, Van Laar and Wilson activity-coeff
Braz. J. Chem. Eng.. Publicado em: 2014-09
-
7. Resgatando um método eficiente para determinação do ponto de ebulição de substâncias orgânicas: percolador versus Siwoloboff
The aim of this paper was to revive the accurate determination of the boiling point of organic compounds using the percolator technique developed in the 1960s. Although this method is simple, fast and efficient it is omitted from current textbooks. This method has several advantages over Siwoloboff such as high reproducibility and direct measurement of the b
Quím. Nova. Publicado em: 2014-06
-
8. Determinação do coeficiente de atividade na diluição infinita em sistemas etanol-água-sal por microextração em fase sólida-gc-fid
A new method using the headspace solid phase microextraction (HS-SPME) technique was used to evaluate the infinite dilute activity coefficient (γ1∞) in an alcohol/water/salt system. The studied systems were ethanol and water with NaCl and NH4Cl at salt concentrations of 5, 10, 15, and 30% m/v and temperatures of 303.15 and 313.15 K. The method was used to
Quím. Nova. Publicado em: 2014
-
9. Modeling vapor liquid equilibrium of ionic liquids + gas binary systems at high pressure with cubic equations of state
Ionic liquids (IL) have been described as novel environmentally benign solvents because of their remarkable characteristics. Numerous applications of these solvents continue to grow at an exponential rate. In this work, high pressure vapor liquid equilibria for 17 different IL + gas binary systems were modeled at different temperatures with Peng-Robinson (PR
Braz. J. Chem. Eng.. Publicado em: 2013-03
-
10. Determinação de parâmetros de equações de estado para líquidos iônicos a partir de dados de velocidade do som / Determination of parameters of equation of state for ionic liquids through speed of sound data
Os líquidos iônicos são compostos químicos cujas propriedades termofísicas têm sido estudadas a fim de aplicá-los em diversos processos, tais como o de separação. No caso da destilação, para realizar o projeto, otimização e a operacao do sistema, necessita-se conhecer o equilíbrio liquida-vapor, cujo calculo pode ser realizado por equações de
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 29/06/2012
-
11. Integração do processo de cristalização de frutose por adição de antissolvente
Fructose (C6H12O6) is a monosaccharide with increasing industrial interest, and with some advantages over other sugars, facts that have motivated many studies about its production from its aqueous solution, by crystallization. Fructose crystallization occurs, in general, with the addition of ethanol as anti-solvent, aiming the reduction of its solubility and
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 29/03/2012
-
12. Modelagem de equilíbrio líquido-líquido, líquido-vapor e líquido-líquido-vapor para sistemas binários, ternários, quaternários e pseudo-quaternários, envolvendo a produção de biodiesel / Modeling of liquid-liquid, liquid-vapor and liquid-liquid-vapor equilibria for binary, ternary, quarternay and pseudo-quaternary systems involving biodiesel production
The worldwide energy demand increases every year. This demand will reach levels that cannot be supplied by current conventional fossil fuel resources. In this context, biofuels arise as a growing primary source of energy, raising research opportunities and encouraging technology development. An important technical issue related to biofuels development is the
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 19/01/2012