Thermodynamics
Mostrando 1-12 de 511 artigos, teses e dissertações.
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1. Hybrid MAPbI3 Perovskite Growth Mechanism from Irregular Particles to Cuboid and Hopper-Type Morphologies
Methylammonium lead iodide (MAPbI3), used as light-harvesting layer in solar cell devices, has attracted great attention from scientific community due to its excellent photovoltaic performance. In this work, we have shown a comprehensive study on the hybrid organic-inorganic MAPbI3 perovskite growth mechanism from irregular small particles to cuboid shape fo
Journal of the Brazilian Chemical Society. Publicado em: 2022
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2. Unified comprehension of the kinetics of isothermal ceramic processes under field-free and resonant wave-field conditions
Abstract This paper proposes a unified comprehension of the isothermal ceramic process kinetics stemming from mesoscopic irreversible thermodynamics. Accordingly, a unified process kinetic equation (UPKE) is derived, which predicts that the global isothermal process rate of any ceramic process is, in general, nonlinearly related both to its activation energy
Cerâmica. Publicado em: 2021-03
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3. Exact and inexact differentials in the early development of mechanics and thermodynamics
Abstract We give an account and a critical analysis of the use of exact and inexact differentials in the early development of mechanics and thermodynamics, and the emergence of differential calculus and how it was applied to solve some mechanical problems, such as those related to the cycloidal pendulum. The Lagrange equations of motions are presented in the
Rev. Bras. Ensino Fís.. Publicado em: 02/12/2019
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4. Thermodynamic Potentials and Natural Variables
Abstract Most books on Thermodynamics explain what thermodynamic potentials are and how conveniently they describe the properties of physical systems. Certain books add that, to be useful, the thermodynamic potentials must be expressed in their “natural variables”. Here we show that, given a set of physical variables, an appropriate thermodynamic potenti
Rev. Bras. Ensino Fís.. Publicado em: 02/12/2019
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5. Evaluation of the Heat and Energy Performance of a Datacenter Using a New Efficiency Index: Energy Usage Effectiveness Design – EUED.
Abstract Data Centers are growing steadily worldwide, and they are expected to continue growing up to 53% in 2020. Energy efficiency, in high power consumption, is a key venue. There are methodologies to measure this efficiency, one example is using the PUE (Power Usage Effectiveness) index. In this paper is proposed a new index for measuring efficiency at
Braz. arch. biol. technol.. Publicado em: 25/11/2019
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6. Activated carbon loaded with manganese and iron for glyphosate adsorption: Kinetics, isotherms and thermodynamic studies
Resumo Carvão ativado granular foi impregnado com 1% de ferro e 0,5% de manganês (m/m) para remoção de glifosato em soluções aquosas. O adsorvente foi caracterizado por microscopia eletrônica de varredura, espectroscopia de energia dispersiva, técnicas de adsorção de nitrogênio e análises de potencial zeta. Estudos em batelada foram realizados pa
Rev. Ambient. Água. Publicado em: 25/11/2019
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7. Kinetics of the Carbonation Reaction of Lithium Orthosilicate Using a Typical CO2 Concentration of Combustion Gases
The aim of this work was to investigate the carbonation kinetics of lithium orthosilicate (Li4SiO4) by thermogravimetry and via thermodynamic simulations, using CO2 concentrations of 15 vol.% (typical of combustion gases) and 100 vol.%. Tests were performed in a thermogravimetric analyzer, in two sequential steps: (1) pre-treatment at 750 ºC with N2 and (2)
Mat. Res.. Publicado em: 05/09/2019
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8. MÁQUINA E REALIDADE: CIBERNÉTICA, AUTOPOIESE E PRODUÇÃO DE SUBJETIVIDADE EM FÉLIX GUATTARI
RESUMO O presente artigo tem como objetivo abordar o conceito de máquina e a consequente apropriação do mesmo nas discussões sobre a subjetividade. É um estudo teórico na interface entre psicologia, filosofia, física e biologia. Nesse sentido, ele se inicia apresentando que, na modernidade, a analogia à máquina foi estendida à compreensão do unive
Psicol. Estud.. Publicado em: 01/08/2019
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9. Variação da entropia total para um corpo em contato com reservatórios térmicos: o caminho da reversibilidade
Resumo A segunda lei da termodinâmica é um dos tópicos de física fundamental menos compreendidos por estudantes e profissionais de ciências exatas e engenharias, talvez devido à sua sutileza e abundância de enunciados. Neste trabalho analisamos a variação de entropia de um sistema isolado, formado por um corpo de capacidade calorífica C(T) e um ou
Rev. Bras. Ensino Fís.. Publicado em: 23/05/2019
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10. UMA AULA DE WALTHER NERNST NO BRASIL
Walther Hermann Nernst is known to have established the basis for the third law of thermodynamics and also as one of the founders of the modern physical chemistry. For his work in chemical thermodynamics, he was awarded the Nobel Prize in chemistry, in 1920. An important fact about this scientist life, not always realized, was his stay in Brazil, in 1914, fo
Quím. Nova. Publicado em: 02/05/2019
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11. Reduction Potential of RuIII-Based Complexes with Potential Antitumor Activity and Thermodynamics of their Hydrolysis Reactions and Interactions with Possible Biological Targets: a Theoretical Investigation
In this article density functional theory (DFT)-based calculations were employed to investigate the electrochemistry of the antitumor ruthenium complexes trans-tetrachloro(dimethylsulfoxide)imidazole ruthenate(III) (NAMI-A) and trans-[tetrachlorobis(1.-indazole)ruthenate(III)] (KP1019), their hydrolysis products as well as their interactions with biological
J. Braz. Chem. Soc.. Publicado em: 2019-03
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12. Isqueiro Pneumático: uma ferramenta versátil ao ensino interdisciplinar
Resumo O isqueiro pneumático é um equipamento que permite produzir fogo por meio de rápida compressão do ar e, quando construído com tubo de acrílico transparente, é possível observar a queima de uma pequena amostra de algodão colocada em seu interior. Por ser um instrumento pouco conhecido e cujo funcionamento chama a atenção vislumbramos seu uso
Rev. Bras. Ensino Fís.. Publicado em: 04/02/2019