Ionic Liquids
Mostrando 1-12 de 102 artigos, teses e dissertações.
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1. Sustainable and Reusable Sulfonic Acid-Functionalized Task-Specific Ionic Liquid Catalysts for Multicomponent Reactions. A Review
Improvements in Sustainable Organic Synthesis are usually related to the investigation of less hazardous, non-corrosive and renewable materials, as well as waste prevention, energy efficiency, solvent-free reactions, and the development of efficient reusable catalysts. In this context, multicomponent reactions emerged as important strategies for the rapid an
Journal of the Brazilian Chemical Society. Publicado em: 2022
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2. Thermophysical and Transport Properties of the BaCl2-CsCl High Temperature Ionic Liquid Mixtures
High temperature ionic liquids (HTILs) densities and transport properties for mixtures BaCl2 CsCl, x(BaCl2) = 0-1, have been studied as a function of composition and temperature. In terms of Arrhenius theory, the temperature correlation of all measured properties was made and discussed. Thermodynamic properties (isothermal compressibility, molecular volume,
Journal of the Brazilian Chemical Society. Publicado em: 2022
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3. What is new in non-chromatographic flavonoid purification?
Flavonoids are metabolites occurring in all plant tissues and present different biological activities. They occur in a mixture of similar polarity with laborious separation and purification processes, usually furnishing low yields. Semi-preparative chromatographic methods are universally employed procedures for their isolation. This paper discusses the state
Química Nova. Publicado em: 2022
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4. Voltammetric Generation and Kinetic Stability of Nitro Anion Radical from Nitrofurazone in Ionic Liquids
The nitrofurazone (NF) electrochemical reduction has been studied by cyclic voltammetry (CV) and square wave voltammetry (SWV) in non-aqueous medium using three different ionic liquids (IL): BMImTf2N, BMImBF4 and BMMImTf2N, having a carbon fiber microelectrode as working electrode. In all of them, two reversible cathodic peaks were recorded for NF. Under hig
J. Braz. Chem. Soc.. Publicado em: 2021-04
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5. Mechanistic Investigation of DBU-Based Ionic Liquids for Aza-Michael Reaction: Mass Spectrometry and DFT Studies of Catalyst Role
1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-based ionic liquids (ILs) has exhibited a high catalytic activity in the aza-Michael reactions compared to conventional catalysts and with imidazole-based ILs. In the present work DBU-based ILs showed high catalytic potential for aza-Michael addition of aromatic amines to 2-cyclohexen-1-one under solvent-free conditio
J. Braz. Chem. Soc.. Publicado em: 2020-09
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6. Polyurethane/poly (Ionic Liquids) Cellulosic Composites and their Evaluation for Separation of CO2 from Natural Gas
The development of both versatile and inexpensive sorbents for CO2/CH4 separation has become one of the greatest challenges to the environment and natural gas processing. This study reports the preparation and characterization of polyurethane (PU)/ cellulose based poly(ionic liquid)(CPIL) composites for CO2/CH4 separation. PU matrix was reinforced with CPIL
Mat. Res.. Publicado em: 20/01/2020
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7. Imidazolium-based Ionic Liquids Impregnated in Silica and Alumina Supports for CO2 Capture
Ionic liquids (ILs) physical immobilization in solid materials is a key strategy for developing efficient and low cost CO2 capture processes. In this work, two porous commercial substrates with different characteristics (silica and alumina) were impregnated with ILs by physical wet method. Imidazolium based IL combined with [Br]- and [Tf2N]- anions were used
Mat. Res.. Publicado em: 11/11/2019
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8. Thermal Stability and Kinetic of Decomposition of Mono- and Dicationic Imidazolium-Based Ionic Liquids
Phase transitions, thermal stability, thermokinetics and activation parameters of degradation reaction of the dicationic ionic liquids (ILs), 1,n-bis(3-methylimidazolium-1-yl)alkane ([BisAlk(MIM)2][2Br]) and monocationic ILs, 1-(3-methylimidazolium-1-yl)alkane ([Alk(MIM)][Br]), where Alk = Dec, DoDec, TetDec, (decane, dodecane, tetradecane) were evaluated. T
J. Braz. Chem. Soc.. Publicado em: 21/10/2019
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9. SYNTHESIS OF MORPHOLINE-BASED IONIC LIQUIDS FOR EXTRACTIVE DESULFURIZATION OF DIESEL FUEL
Abstract Extractive desulfurization with ionic liquids has attracted significant attention from a growing number of scientists due to the current environmental restrictions on fuel. Protic ionic liquids (PILs) were synthesized via equimolar neutralization of morpholine and formic-based compounds. The obtained PILs were characterized by Fourier transform infr
Braz. J. Chem. Eng.. Publicado em: 30/09/2019
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10. THERMAL CONDUCTIVITY ENHANCEMENT OF AQUEOUS IONIC LIQUID AND NANOPARTICLE SUSPENSION
Abstract In the present study, the thermal conductivities of ionic liquid + water in the concentrations 0.1-0.6 %w/w and temperatures (302.5-337.9 K) are determined. The thermal conductivity of aqueous 1-butyl-3-methylimidazolium bromide declined with increasing concentration and temperature. A quadratic model is developed for predicting the thermal conducti
Braz. J. Chem. Eng.. Publicado em: 30/09/2019
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11. Termogravimetric Characterization of Biomass Impregnated with Biodegradable Ionic Liquids
ABSTRACT Different classes of solvents such as mineral acids and ionic liquids have proved to be capable of disrupting hydrogen bonds among different polysaccharide chains. Recently, a specific family of proticionic liquids (PILs) has been developed with functionality in various industrial applications, adding to the benefits and advantages of their use, sin
Floresta Ambient.. Publicado em: 23/09/2019
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12. Liquid-liquid equilibria in aqueous two-phase ethanol/salt systems at different temperatures and their application to anthocyanins extraction
Abstract Aqueous two-phase systems (ATPS) are formed by mixtures of chemical species that, under certain conditions, separate into two immiscible phases, with water as the major component in global terms and, at lower concentrations, polymers, salts, ionic liquids and alcohols, depending on the system type. Different parameters influence ATPS equilibrium suc
Food Sci. Technol. Publicado em: 16/05/2019