Flow Injection Spectrophotometry
Mostrando 1-12 de 16 artigos, teses e dissertações.
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1. Determinação espectrofotométrica de cloreto em cimento após preparo de amostra por piroidrólise
A method based on pyrohydrolysis was proposed for cement sample preparation and further chloride determination by spectrophotometry using flow injection analysis. Analytical parameters were evaluated and, under the selected conditions, the calibration curve was linear in the range of 0.2 to 10.0 µg mL-1 with r2 = 0.998. The limit of detection was5 µg g-1 o
Quím. Nova. Publicado em: 2013
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2. Especiação redox de crômio em amostras de solos contaminados / Redox especiation of chromium in contaminated soil samples
Chromium and its compounds are employed in various industrial processes, and these activities are responsible for the disposal of significant amounts of materials containing this element in the environment. Due to the known toxic feature of Cr(VI) in biological systems, the determination of chromium species has acquired great importance in environmental chem
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 21/03/2012
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3. Projeto e desenvolvimento de um sistema de análises químicas por injeção em fluxo para determinações espectrofotométricas simultâneas de cobre e de níquel explorando cinética diferencial e calibração multivariada / Project and development of a flow-injection system for simultaneous spectrophotometric determination of copper and nickel exploiting differential kinetics and multivariate calibration
Análise cinética diferencial explora diferenças em taxas reacionais entre os analitos e um sistema reacional comum; etapas de separação prévia dos analitos podem então ser prescindidas. Sistemas de análise por injeção em fluxo (FIA) se afiguram como uma ferramenta importante para métodos envolvendo essa estratégia, pois permitem um controle preci
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 09/06/2011
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4. Desenvolvimento de instrumentação e procedimentos analíticos automáticos empregando fotometria em fase sólida para determinação de zinco em produtos farmacêuticos e água / Combining multicommuted flow injection analysis and solid phase photometry for the determination of zinc in pharmaceutical preparation and water
Neste trabalho, é proposto o desenvolvimento de instrumentação e procedimentos analíticos automáticos empregando fotometria em fase sólida para determinação de zinco em produtos farmacêuticos e água. Para implementação do procedimento analítico, todo o sistema foi acoplado a um computador através de uma interface eletrônica. Um software escrit
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 25/08/2010
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5. Determinação espectrofotométrica de selênio em rações para animais empregando análise por injeção em fluxo / Spectrophotometric determination of selenium in ration for domestic animals employing flow injection analysis
In this work it was developed an automatic procedure for the determination of selenium in ration for domestic animals digested in acidic medium. The automated method was based on the catalytic effect caused by selenium (IV) on the reaction of ammoniacal iron sulfate with EDTA in medium containing NaNO3. The analytical module was based on multicommuted flow p
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 20/10/2008
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6. Molecularly imprinted polymers (MIPs) as solid phase extractors in flow systems / Polímeros molecularmente impressos (MIPs) como extratores em fase sólida em sistemas de análises em fluxo
Molecularly imprinted polymers (MIPs) are promising as material to be used in solid phase extractions due to their high selectivity. MIPs selectivity is directly related to the recognition of a molecule of interest, which was previously employed as template in the synthesis process. The main favorable characteristics of MIPs are the easy preparation, low cos
Publicado em: 2008
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7. Development of flow procedures involving conventional spectrophotometry and long pathlenght for determination of anions in waters / Desenvolvimento de procedimentos em fluxo envolvendo espectrofotometria convencional e com longo caminho óptico para determinação de ânions em águas
In this work, five procedures were developed for determination of anions (chloride, sulphate, phosphate and fluoride), with spectrophotometric detection, being four employing a 100-cm optical length flow-cell and one of them employing a cell whith 1 cm optical length. The first procedure employing flow injection analysis with long pathlenght for chloride det
Publicado em: 2008
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8. Studies about the adsorption of di-2-pyridyl ketone salicyloylhydrazone (DPKSH) on Amberlite XAD-2 and XAD-7 resins. Extraction of ion Cu(II) using the solid phase XAD-7 modified with DPKSH / Estudos de adsorção de di-2-piridil cetona saliciloilhidrazona (DPKSH) em resinas amberlite xad-2 e xad-7. Extração de íons cobre em fase sólida envolvendo a xad-7 modificada com DPKSH
Di-2-pyridyl ketone salicyloylhydrazone (DPKSH) is a hydrazone which forms coordination compounds with several metallic ions. Amberlite XAD-2 and XAD-7 resins are non-ionic polymers which can be used to pre-concentrate metallic ions. Adsorption of DPKSH onto these polymeric matrices was investigated using the spectrophotometry. The amount of DPKSH adsorbed o
Publicado em: 2007
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9. Desenvolvimento e validação de metodologia para medicamentos contendo dipirona sódica e cloridrato de papaverina isolados e em associação / Develop and validate analytical methods for determination of dipyrone sodium and papaverine hydrochloride in pharmaceutical preparations
Dipyrone sodium and papaverine hydrochloride are used as an analgesic and antispasmodic drugs. The objective of this study was to develop and validate analytical methods for determination of dipyrone sodium and papaverine hydrochloride in pharmaceutical preparations. The commercial formulations with dipyrone hydrochloride alone and its combination with papav
IBICT - Instituto Brasileiro de Informação em Ciência e Tecnologia. Publicado em: 31/01/2006
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10. "Multivariate calibration and differential kinetic analysis in flow systems with spectrophotometric detection" / "Calibração multivariada e cinética diferencial em sistemas de análises em fluxo com detecção espectrofotométrica"
Differential kinetic analysis can be implemented in a flow system analyser, and this was demonstrated in designing an improved spectrophotometric catalytic determination of iron and vanadium in Fe-V alloys. The method relied on the influence of Fe2+ and VO2+ on the rate of the iodide oxidation by Cr2O7 under acidic conditions; therefore the Jones reductor wa
Publicado em: 2006
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11. "Sistemas de análises químicas em fluxo explorando multi-impulsão e detecção espectrofotométrica: aplicação a formulações farmacêuticas e a extratos de solos" / Multi-pumping flow systems with spectrophotometric detection: application to analysis of pharmaceuticals and soil extracts
Multi-pumping flow systems (MP) utilize solenoid pumps as fluid propelling devices, which deliver pulsed flows. This feature was evaluated in relation to the design, operation and performance of the system, to the mixing conditions, and to the dispersion of the introduced solution. The general evaluation of the MP systems involved investigations about precis
Publicado em: 2006
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12. "Development of the instrumentation and automatic analytical procedures for spectrophotometric determination of surfactants in waters" / "Desenvolvimento de instrumentação e procedimentos analíticos automáticos para a determinação espectrofotométrica de tensoativos em águas"
"In this work, development of the instrumentation and automatic analytical procedures for spectrophotometric determination of surfactants in waters employing the multicommutation concept were proposed. Aiming to system miniaturization, reduction of reagents consumption and effluents generation, solenoids micro-pump and solenoids pinch valves were used for th
Publicado em: 2006