Analytical Chemistry
Mostrando 13-24 de 174 artigos, teses e dissertações.
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13. Vibrational Spectroscopy and Chemometrics in Forensic Chemistry: Critical Review, Current Trends and Challenges
The present manuscript makes an extensive review of the scientific approaches developed in the last decade involving infrared and Raman spectroscopy combined with chemometrics for solving several issues in the investigation of the most relevant forensic traces, such as questioned documents and currency, explosives, gunshot residues, illicit drugs and body fl
J. Braz. Chem. Soc.. Publicado em: 24/10/2019
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14. EL DOPAJE DEPORTIVO COMO CUESTIÓN SOCIALMENTE VIVA: UNA REVISIÓN BIBLIOGRÁFICA
This paper aims to present a review of the concept doping in scientific journals published in the period 2008 to 2018. The diversity of approaches that position doping as a socially acute question (SAQ) allow us to recognize the implications of this concept in educational contexts. The state of the art methodology seeks to reflexively recover production on t
Quím. Nova. Publicado em: 21/10/2019
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15. LASER INDUCED-BREAKDOWN SPECTROSCOPY (LIBS): HISTÓRICO, FUNDAMENTOS, APLICAÇÕES E POTENCIALIDADES
This review attempts to present a broad view of the technique laser-induced breakdown spectroscopy (LIBS), since its origin, fundamentals, sample preparation strategies, use of chemometric tools for data processing, the advantages and limitations with regard to qualitative and quantitative analysis, aplications and future trends as an analytical technique th
Quím. Nova. Publicado em: 18/07/2019
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16. DETERMINAÇÃO DE Al3+, Fe3+ E Cu2+ PRESENTES EM SOMBRAS DE MAQUIAGEM POR ESPECTROFOTOMETRIA UV-Vis: UMA PROPOSTA DE EXPERIMENTO CONTEXTUAL EM NÍVEL SUPERIOR DE ENSINO
Metallic oxides are used in cosmetic shadows formulations in order to highlight the area around the eyes, with different colors. Due to the close proximity to the eye mucosa, these products are a potential source of metal intoxication in human body. Based in this fact, several analytical methods to quantify metals in cosmetic shadows have been proposed in th
Quím. Nova. Publicado em: 02/05/2019
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17. FOTOCATÁLISE MEDIADA POR TiO2 NO ESTADO NANOPARTICULADO: REVISÃO DA REATIVIDADE PELO CONCEITO DE TRAPS E ALGUMAS APLICAÇÕES EM QUÍMICA ANALÍTICA
TiO2 has been used as a white pigment and studied since the first decades of the XX century for the undesirable chalking of outdoor paintings exposed to sunlight. Since the first report of Honda and Fujishima (1972) of the water splitting by the harvesting of sunlight on a n-type single crystal TiO2 electrode, the engagement of researchers with the field has
Quím. Nova. Publicado em: 02/05/2019
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18. An overview of the Brazilian contributions to Green Analytical Chemistry
Abstract: Green Analytical Chemistry (GAC) is a research field that seeks for more sustainable analytical approaches to minimize the toxicity and amounts of wastes without hindering the analytical performance. This is a trend in Analytical Chemistry worldwide and because of the diversity of innovations on this subject, Brazil stands out as the third in the l
An. Acad. Bras. Ciênc.. Publicado em: 18/04/2019
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19. A Novel Thermal Infrared Enthalpimetric Method for Fast, High-Throughput Determination of the Content Uniformity of Captopril Tablets
Content uniformity (CU) is a parameter used to ensure the uniformity of the amount of active substances in pharmaceutical preparations. It is often evaluated in the quality control of pharmaceutical dosage forms, and a novel method was proposed for CU determination using thermal infrared enthalpimetry (TIE). Captopril tablets were dissolved in 24-well microp
J. Braz. Chem. Soc.. Publicado em: 08/04/2019
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20. RM1 Semiempirical Model: Chemistry, Pharmaceutical Research, Molecular Biology and Materials Science
In this review, we show improvements to the semiempirical quantum chemical method RM1 and present a wide range of its applications as reported by researchers of various areas, such as theoretical, organic, physical, analytical, and inorganic chemistry, as well as their interfaces with medicinal chemistry, biology, and materials science. Success of RM1 is see
J. Braz. Chem. Soc.. Publicado em: 2019-04
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21. Use of Natural Deep Eutectic Solvents for Polymerization and Polymer Reactions
Green chemistry is a key opportunity in chemistry and chemical engineering today because it can potentially preserve the environment and human health. It entails the choice of natural biodegradable raw materials and solvents, environmentally acceptable processes, and minimal use of non-hazardous chemicals. Previously, deep eutectic solvents (DES) have found
J. Braz. Chem. Soc.. Publicado em: 2019-04
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22. Green Chemistry Method Based on PARAFAC EEM Data Modeling for Benzo[a]pyrene Quantitation in Distilled Spirit
Benzo[a]pyrene (BaP) is often used as a marker of polycyclic aromatic hydrocarbons (PAHs) in beverages. This marker is often quantified by chromatographic methods, which require sample preparations involving the use of reagents, solvents, extraction, pre-concentration, and/or cleanup steps. In this study, a new method for quantification of BaP in cachaças (
J. Braz. Chem. Soc.. Publicado em: 2019-02
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23. Removal of synthetic sex hormones by hydrothermal carbonization
ABSTRACT One of the most prominent fields of environmental chemistry is the study and the removal of micro-pollutants from aqueous matrices. Analytical techniques for their identification and quantification are becoming more sensitive and comprehensive and, as a result, an increasing number of drugs have been detected in environmental samples. However, the l
An. Acad. Bras. Ciênc.. Publicado em: 14/05/2018
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24. Flow Analysis: Looking Back and Forward
Flow analysis changed significantly the way of performing chemical analysis by (i) mechanization of analytical procedures in a continuous flowing stream with minimal sample intercontamination; (ii) analytical measurements without attaining chemical equilibria, thus increasing the applicability of kinetic methods and allowing the exploitation of non-quantitat
J. Braz. Chem. Soc.. Publicado em: 2018-05